- Most Rev. Samineni Arulappa
- Second Archbishop of Hyderabad
- 1972 - 2000
- Most Rev. Joseph Mark Gopu
- First Archbishop of Hyderabad
- 1953 - 1957
- Most Rev. Marampudi Joji
- Third Archbishop of Hyderabad
- 2000 - 2010
- Most Rev. Thumma Bala
- Fourth Archbishop of Hyderabad
- 2011 - 2020
- Most Rev. Poola Anthony
- Fifth Archbishop of Hyderabad
- 2021 - Present